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Catalytic Acetylation of Anisole with Ce-
β/MCM-41
Liu Han,Li Huipeng,Zhao Hua,Jiao Lei
With CTAB as template, the
β/MCM-41 micro-mesoporous composite molecular sieve has been synthesized by self-assembly of the zeolite structure fragments and the structural units obtained by alkali-treated
β zeolite, and the effects of the alkali solution concentration, CTAB dosage in the synthesis process of
β/MCM-41 was investigated. The
β/MCM-41 composite molecular sieve with well long-range order can be synthesized under the optimum conditions: The solution concentration of NaOH is 1.5 mol/L and the mass fraction of CTAB is 10%. Then the Ce-
β/MCM-41 composite molecular sieve doped skeleton with rare earth metal Ce was synthesized and the effect of Ce doping amount (Ce/
β=0.03, 0.08) on Ce-
β/MCM-41 was investigated. The result shows that the 0.03-Ce-
β/MCM-41 had a well long-range order. The effect of acetylation reaction conditions on the yield of
p-MOAP was investigated by using 0.03-Ce-
β/MCM-41 as a catalyst in a fixed bed. The single-factor experiments showes that the 4.0 h
p-MOAP yield is 58.6% under the conditions: The velocity of the reactants flow is 65 mL/h, the LHSV is 6.5 h
-1, reaction temperature is 140 ℃ and n(AN)/n(AA)=6.0.
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